To calculate the correct value for shared_buffers in a AWS RDS PostgreSQl database:
(2*1024*1024*12.5/100)/8)
# = 32768
The values:
2*1024*1024- DB instance has 
2 [GB]of RAM. 1024*1024convertsGBtokB.
- DB instance has 
 12.5/10012.5 [%]of the RAM should be assigned toshared_buffers.
/8- Postgres works with blocks of 
8 [kB]size. 
- Postgres works with blocks of 
 
So, if you would like to increase the value for shared_buffers to 25 [%] (instead of 12.5 [%]), you would want to have:
(2*1024*1024*25/100)/8)
# = 65536