current config

apiVersion: v1
kind: ConfigMap
metadata:
  name: prometheus-server-conf
  labels:
    name: prometheus-server-conf
  namespace: monitoring
data:
  prometheus.yml: |-
    global:
      scrape_interval: 55s
      evaluation_interval: 55s

    scrape_configs:
      - job_name: 'kubernetes-apiservers'

        kubernetes_sd_configs:
        - role: endpoints
        scheme: https

        tls_config:
          ca_file: /var/run/secrets/kubernetes.io/serviceaccount/ca.crt
        bearer_token_file: /var/run/secrets/kubernetes.io/serviceaccount/token

        relabel_configs:
        - source_labels: [__meta_kubernetes_namespace, __meta_kubernetes_service_name, __meta_kubernetes_endpoint_port_name]
          action: keep
          regex: default;kubernetes;https

      - job_name: 'kubernetes-nodes'

        scheme: https

        tls_config:
          ca_file: /var/run/secrets/kubernetes.io/serviceaccount/ca.crt
        bearer_token_file: /var/run/secrets/kubernetes.io/serviceaccount/token

        kubernetes_sd_configs:
        - role: node

        relabel_configs:
        - action: labelmap
          regex: __meta_kubernetes_node_label_(.+)
        - target_label: __address__
          replacement: kubernetes.default.svc:443
        - source_labels: [__meta_kubernetes_node_name]
          regex: (.+)
          target_label: __metrics_path__
          replacement: /api/v1/nodes/${1}/proxy/metrics

      
      - job_name: 'kubernetes-pods'

        kubernetes_sd_configs:
        - role: pod

        relabel_configs:
        - source_labels: [__meta_kubernetes_pod_annotation_prometheus_io_scrape]
          action: keep
          regex: true
        - source_labels: [__meta_kubernetes_pod_annotation_prometheus_io_path]
          action: replace
          target_label: __metrics_path__
          regex: (.+)
        - source_labels: [__address__, __meta_kubernetes_pod_annotation_prometheus_io_port]
          action: replace
          regex: ([^:]+)(?::\d+)?;(\d+)
          replacement: $1:$2
          target_label: __address__
        - action: labelmap
          regex: __meta_kubernetes_pod_label_(.+)
        - source_labels: [__meta_kubernetes_namespace]
          action: replace
          target_label: kubernetes_namespace
        - source_labels: [__meta_kubernetes_pod_name]
          action: replace
          target_label: kubernetes_pod_name

      - job_name: 'kubernetes-cadvisor'

        scheme: https

        tls_config:
          ca_file: /var/run/secrets/kubernetes.io/serviceaccount/ca.crt
        bearer_token_file: /var/run/secrets/kubernetes.io/serviceaccount/token

        kubernetes_sd_configs:
        - role: node

        relabel_configs:
        - action: labelmap
          regex: __meta_kubernetes_node_label_(.+)
        - target_label: __address__
          replacement: kubernetes.default.svc:443
        - source_labels: [__meta_kubernetes_node_name]
          regex: (.+)
          target_label: __metrics_path__
          replacement: /api/v1/nodes/${1}/proxy/metrics/cadvisor
      
      - job_name: 'kubernetes-service-endpoints'

        kubernetes_sd_configs:
        - role: endpoints

        relabel_configs:
        - source_labels: [__meta_kubernetes_service_annotation_prometheus_io_scrape]
          action: keep
          regex: true
        - source_labels: [__meta_kubernetes_service_annotation_prometheus_io_scheme]
          action: replace
          target_label: __scheme__
          regex: (https?)
        - source_labels: [__meta_kubernetes_service_annotation_prometheus_io_path]
          action: replace
          target_label: __metrics_path__
          regex: (.+)
        - source_labels: [__address__, __meta_kubernetes_service_annotation_prometheus_io_port]
          action: replace
          target_label: __address__
          regex: ([^:]+)(?::\d+)?;(\d+)
          replacement: $1:$2
        - action: labelmap
          regex: __meta_kubernetes_service_label_(.+)
        - source_labels: [__meta_kubernetes_namespace]
          action: replace
          target_label: kubernetes_namespace
        - source_labels: [__meta_kubernetes_service_name]
          action: replace
          target_label: kubernetes_name

this config scrape, if some service is annotated with prometheus.io/scrape: true. this has default scrape time interval 55s. This is defined globally in the beginning of config file. This scraping is defined in job_name. Job_name kubernetes-service-endpoints does this actually.

We can define another job_name (kubernetes-service-endpoints-123) which scrape services for 100s, if services are annotated with prometheus.io/scrape2: true

- job_name: 'kubernetes-service-endpoints-123'
        scrape_interval: 100s
        kubernetes_sd_configs:
        - role: endpoints

        relabel_configs:
        - source_labels: [__meta_kubernetes_service_annotation_prometheus_io_scrape2]
          action: keep
          regex: true
        - source_labels: [__meta_kubernetes_service_annotation_prometheus_io_scheme]
          action: replace
          target_label: __scheme__
          regex: (https?)
        - source_labels: [__meta_kubernetes_service_annotation_prometheus_io_path]
          action: replace
          target_label: __metrics_path__
          regex: (.+)
        - source_labels: [__address__, __meta_kubernetes_service_annotation_prometheus_io_port]
          action: replace
          target_label: __address__
          regex: ([^:]+)(?::\d+)?;(\d+)
          replacement: $1:$2
        - action: labelmap
          regex: __meta_kubernetes_service_label_(.+)
        - source_labels: [__meta_kubernetes_namespace]
          action: replace
          target_label: kubernetes_namespace
        - source_labels: [__meta_kubernetes_service_name]
          action: replace
          target_label: kubernetes_name

If you take a look at 2nd line of job_name: kubernetes-service-endpoints-123 it'll set scrape time to 100s. if some service is annotated with prometheus.io/scrape2: true than it'll scrape for 100 seconds